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Figure 2: DRIFT spectra of the nanoparticle samples NP-RA, NP-MMA and NP-PMMA-3.

Figure 2:

Figure 2: DRIFT spectra of the nanoparticle samples NP-RA, NP-MMA and NP-PMMA-3.

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Three different events can lead to the copolymerization and attachment of the PMMA chains to NP-MMA: i) initiation occurs on the NP-MMA, resulting in PMMA chain(s) growing from the surface of the NP-MMA (blue circle in Scheme1 ); ii) growing PMMA chain(s) copolymerizes with the methacrylate unit(s) on the surface of a single NP-MMA (red circle in Scheme1 ); iii) growing PMMA chain copolymerizes with methacrylate unit(s) on the surface of more than one NP-MMA particle, resulting in the formation of covalent links between the NP-MMA surfaces (green circle in Scheme1 ).

Of the three events, the last one is the most dependent on the concentration of NP-MMA and can even lead to cross-linking. The relative occurrence of this event should have a major influence on the colloidal stability of the NP-PMMA suspension and the hydrodynamic size of the NP-PMMA. The gel properties of the suspension of the NP-PMMA-3, where the concentration of the NP-MMA was the highest, indicate the relatively high content of the PMMA chains connecting several neighboring nanoparticles.

The size of the NP-PMMA-3 nanoparticles and the free PMMA chains were probed using dynamic light scattering (DLS). Two distinct populations were found in the suspension of nanoparticles denoted as NP-PMMA-3 ( Figure3 ).

Figure 3: Number-weighted hydrodynamic diameter size-distribution function of the NP-RA and NP-PMMA-3 nanoparticle samples.

Figure 3:

Figure 3: Number-weighted hydrodynamic diameter size-distribution function of the NP-RA and NP-PMMA-3 nanopar...

Jump to Figure 3

The distribution function for the smaller diameter region was extremely narrow, with the mode at 2 nm. The distribution function for the larger diameter region is strongly skewed and the median, having the value of 45 nm, is a better estimate of the “average” hydrodynamic diameter than the mean or mode. The distribution functions were well separated; therefore, we can conclude that the one centered at 2 nm described the hydrodynamic size of the free polymer chains, and the other one, the NP-PMMA nanoparticles. Additionally, the sPMMA sample was measured. In this case the signal was weak so the autocorrelation function was acquired at a low angle, i.e., at a small scattering vector that makes it possible to probe the fast dynamics of small polymer chains. The resulting distribution function of the hydrodynamic size of the polymer chains was centered at approximately 4 ± 2 nm. The large error is due to the weak signal. On the other hand, in the NP-PMMA-3 sample, the scattering from the nanoparticles overwhelmed the scattering from the small polymer chains, also making an estimation of their size less reliable. We believe that the hydrodynamic diameter of the free PMMA chains being between 1 nm and 4 nm is a valid assumption. The distribution function of the NP-RA nanoparticles is less skewed with a median of 30 nm. The number-weighted average size and the median of the nanoparticles NP-RA determined from the TEM images were 11.0 ± 2.3 nm and 10 nm, respectively ( Supporting Information File1 , Figure S6). Considering the fact that the suspension of NP-RA was colloidal, the relatively large hydrodynamic size is related to the exceedingly good solvation of the RA chains by toluene. The increase in the hydrodynamic size from 30 nm to 45 nm during the polymerization is clearly related to the copolymerization of the NP-MMA and MMA. The relatively large hydrodynamic size and the increased skewness of the hydrodynamic size-distribution function of the NP-PMMA-3 suggest that some NPs were linked together; however, the number of the individual NPs linked together is quite low. This indicates that branched structures with NPs acting as the branching points were most likely formed instead of a fully cross-linked gel. The fact that the hydrodynamic size of the NP-PMMA nanoparticles was still large in the diluted sample was a further proof that the polymer chains were strongly attached, not only adsorbed onto the surface of the nanoparticles.

Even if you have a beautifully designed content rich blog, your site might be a dead-end if it never references all the other blogs, humor sites, search engines, sports teams, or chicken cacciatore recipes you love so much! Since you visit those sites all the time, then use the WordPress Add New Link ability to allow your reading public to also enjoy those sites.

WordPress Links can be organized by category, have internal references about your relationship to their destinations, can be automatically associated with images, and can even be rated on a scale from zero to nine. The Links Manager article provides a good overview of using and administering links.

The All Links Screen allows you to select the Links to edit or delete. Multiple Links can be selected for deletion. Various search and filtering options allow you to find the Links you want to edit or delete.

As you might expect from its name, the Links Add New Screen handles the creation of new links.

Links, like Posts, can be categorized and categorizing Links aids your audience in navigation of your Links. But Link Categories, unlike post Categories, have no hierarchy (parent/child relationship). In creating categories, recognize that each Category name must be unique.

The Links Link Categories Screen allows you to add, edit, and delete Link Categories. Multiple Link Categories can be selected for deletion. A search option allows you to find the Link Categories you want to edit or delete. Also remember Link Categories can be added when adding or editings Links.

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A is another tool to add content to a WordPress site and is often used to present "static" information about the site; Pages are typically "timeless" in nature. A good example of a Page is the information contained in "About" or "Contact" Pages. A Page should not be confused with the time-oriented objects called Posts, nor should a WordPress Page be confused with the word "page" referring to any web page or HTML document on the Web.

Because Pages live outside of the normal blog chronology, and as such, are not displayed with the rest of your Posts, but are displayed individually.

The All Pages Screen provides the necessary tools to edit, delete or view existing Pages. On this Screen you can select the Page to edit, delete or view. Multiple Pages can be selected for deletion and for editing. As with Posts, a powerful bulk edit tool allows certain fields to be edited for a whole group of Pages. A handy in-line edit tool, called Quick Edit, allows you to update many fields for an individual Page. Various search and filtering options allow you to find the Pages you want to edit or delete.

You can read a little bit more about the above-mentioned topics in the article linked below.

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How Some of the World’s Elite Uses Black Magic Rituals To Conjure Up Entities For More Power Control

The sarcophagus wasn’t the only thing discovered in the tomb, there was also an alabaster head of a man who some believe could represent the person who is buried within the coffin.

RT news points out ,

Most ancient tombs discovered in Egypt were looted in one era or another, often leaving archaeologists with a limited understanding of the person inside. This untouched artifact gives the eager team a rare opportunity to uncover the mummy for themselves….Some people suggested the sarcophagus coupled with the recent discovery of a Neolithic henge in Ireland is either a sign of an impending apocalypse… or a very extravagant marketing scheme for a new Indiana Jones movie.

It’s important to close on the note that, not all which has been discovered is presented to us. We live in a world of secrecy, millions of pages of documents are classified every single year, for anybody to study the true history of, let’s say America, it would truly be impossible because it’s incredibly difficult to get something that actually reflects the truth.

I like to use the United States as an example, specifically, the National Security Agency (NSA) which was founded in 1952, its existence was hidden until the mid 60’s. Even more secretive is the National Reconnaissance Office (NRO), which was founded in 1960 but remained completely secret for 30 years.

What about archaeological discoveries, have they been kept from us? What about the Naszca mummies that were discovered in Peru? And all of the other discoveries within the realms of archaeology, like giants , completely left out of the historical record?

Historial and archaeological discoveries have the power to completely change what we know about human history and the origins of humanity. It wouldn’t be surprising that any artifact or physical traces of past life that don’t fit within the frame of accepted knowledge, or within the theory of evolution, to be completely unknown to humanity. This is one of many ways the global elite contain their control over humanity, and over the story of humanities origins.

Definitely, something to think about…

As far as the coffin goes, it looks they’re going to open it for sure…

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We interviewed David about what is happening within the cabal and disclosure. He shared some incredible insight that is insanely relevant to today.

So far, the response to this interview has been off the charts as people are calling it the most concise update of what's happening in our world today.

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When it comes to monogramming, Kelsie Vogds with Must Be Monogrammed is our go to gal! She’s filling us in on all things monogram today and answering all our questions about the etiquette behind branding with initials. Take a peek below at our QA, then head to Must Be Monogrammed to shop pieces for the wedding day, post-wedding or pre-wedding gifts!

In what order should a couple’s initials be listed in a monogram?

A monogram can be listed a few different ways.

Option 1: Individual monogram for the bride or the groom. These will appear one of two ways depending on the font/style.

Style One: Larger Middle Letter

Traditionally, a monogram reads First Name Initial, Last Name Initial, Middle Name or Maiden Name Initial. With the Last Name Initial being the larger Middle Initial. For example, if you had the name Kelsie Elizabeth Vogds, her monogram would read KVE.

Style Two: Letters All the Same Size or Block Monogram

This style of monogram traditionally reads First Name Initial, Middle Name Initial, Last Name Initial with all the letters being the same size in line with one another. For example, if you had the name Kelsie Elizabeth Vogds, her monogram would read KEV.

Option 2: His and Hers Monogram

There are two schools of thought on the order in which a couple’s monogram should appear and either order is acceptable. We recommend that once an order for initials is decided on that all future items are monogrammed in this same order for aesthetic purposes, but that’s just us! There’s no right or wrong way to style your family monogram!

Style One: Ladies First

The wife’s first name initial, the couple’s married last name initial in the center and largest letter followed by the husband’s first name initial. For example, Kelsie Brice Robinson would be KRB.

Style Two: Mr. Mrs.

If you’re all for tradition, then you could have your monogram appear in the order husband’s first name initial with the last name initial larger in the middle and the wife’s first name initial last. The theory here and that a man’s first name and last name should not be separated.


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